Now its time to get the emulaotr. I suggest and No$gba (I think pokemon diamond/pearl is only compatible with No$gba). Then open your rom with no$gba. When your done that, post what happens and if it doesnt work you can post some more questions. You can also look around here. Lately, theres been lots of threads about pokemon diamond/pearl.
BTW, No$gba cant play zipped.


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Google is your friend too. 