ePSXe and PSX are the most widely used. PSX is the easiest to setup and use but ePSXe uses various plugins to provide enhanced graphics and sound.
Both are available from this site. You will need the PS1 bios files to run them. Your best bet to obtain the bios would be to use a search engine like google as the rules here prevent discussion of where to obtain IP that's subject to copyright.
Both emulators support playing games from ISO's or directly from the original disks.
Hope that helps.


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