You don't unzip mame roms, just leave them zipped and put them in the mame\roms folder.
For neogeo games to work you also need the NeoGeo bios in your mame\roms folder. The file is called neogeo.zip although the forum rules prohibit providiing information on where to obtain it (googles handy though). Just like the game roms you leave this zipped and place it in the mame\roms folder.
There are a number of arcade systems in mame that require a bios rom as well as a game rom to work with mame. Googling mame bios roms or visiting the Maws webpage should yield helpful results.
Once you have added any new (zipped) roms to the rom folder select 'file' from the Mame32 toolbar and then 'audit all'. Now your games will run if you have the correct roms.
Lastly remember some games have several variants (clones) but only one version will be the parent rom. A parent rom contains all files for the game and the clones won't run without it.


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